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 | PERSPECTIVES IN ORGANOPALLADIUM CHEMISTRY FOR THE 21ST CENTURY
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By
J. Tsuji, Kurashiki University of Science and the Arts, Department of Chemical Technology, Tsurajima, Kurashiki, Okayama 712, Japan
Description
Perspectives in Organopalladium Chemistry for the 21st Century is a monograph on modern organopalladium chemistry, with an emphasis on
the use of palladium in organic synthesis. The collection of articles is reprinted from a special issue of the Journal of Organometallic
Chemistry.
The field of organopalladium chemistry is evolving rapidly, building on a growing catalogue of reactions that employ palladium-containing
catalysts. This book should hold particular interest for those who apply palladium reagents and catalysts to organic synthesis; in
fact, palladium is considered by many to be the most useful transition element employed for organic syntheses.
This selection of articles
by leading scientists, published as "Perspectives in Organopalladium Chemistry for the 21st Century", provides an impressive overview
of the field that every chemist who works with organometallic palladium catalysts should read.
Audience
Applied Research Scientists, Inorganic and Organic Chemists.
Contents
• The Palladium-Catalyzed Arylation and Vinylation of Alkenes - Enantioselective Fashion. (Masakatsu Shibasaki, E.M. Vogl).
•
Enantioselective Heck Reactions Using Chiral P, N-Ligand. (O. Loiseleur, Masahiko Hayashi, M. Keenan, N. Schmees, A. Pfaltz).
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Applications of Palladacycles in Heck-Type Reaction. (W.A. Herrmann, C.-P. Reisinger, V.P.W. Böhm).
• Heterocycles via
Cyclization of Alkynes Promoted by Organopalladium Complexes. (S.Cacchi).
• Palladium in Action: Domino and Cascade Coupling
Reactions for the Efficient Construction of Complex Organic Molecules. (A. de Meijere).
• Palladium-Catalyzed Cascade Cyclization-Anion
Capture, Relay Switches and Molecular Queues. (R. Grigg and V. Sridharan).
• Palladium-Catalyzed Annulation. (R. Larock).
•
Palladium-Catalyzed Amination of Aryl Halides and Sulfonates. (B.H. Yang and S.L. Buchwald).
• Recent Advances in the Cross-Coupling
Reactions of Organoborane Derivatives with Organic Electrophiles, 1995-1998. (Akira Suzuki).
• The Palladium-Iminophosphine Catalyst
for the Reactions of Organostannanes. (Eiji Shirakawa and Tamejiro Hiyama).
• Novel and Selectiveα-Substitution of Ketones
and Other Carbonyl Compounds Based on Pd-Catalyzed Cross Coupling of αβ-Unsaturated Carbonyl Derivatives Containing α-Halogen
or α-Metal Groups. (Ei-ichi Negishi).
• Catalytic Asymmetric Reactions via π-allylpalladium Complexes Coordinated with
Chiral Monophosphine Ligands. (Tamio Hayashi).
• Enantioselective Palladium-Catalyzed Allylic Substitutions with Asymmetric Chiral
Ligands. (G. Helmchen).
• Novel Catalytic Reactions Involving π-Allylpalladium and -nickel as the Key Intermediates; Umpolung
and β-Decarbopalladation of π-Allylpalladium and Nickel-catalyzed Homoallylation of Carbonyl Compounds with 1,3-Dienes. (Yoshinao
Tamaru).
• Recent Development of Palladium(O) Catalyzed Reactions in Aqueous Medium. (J.P. Genet and M. Savignac).
•
Palladium-Catalyzed Enyne-Yne [4+2] Benzannulation as a New and General Approach to Polysubstituted Benzenes. (V. Gevorgyan and Yoshinori
Yamamoto).
• Steroselective Alternating Copolymerization of Carbon Monoxide with Alkenes. (Kyoko Nozaki and Tamejiro Hiyama).
•
Mechanistic and Kinetic Studies of Palladium Catalystic Systems. (C. Amatore and A. Jutand).
• Oxidative Reactions by Palladium-Alkyl
Nitrite System. (Shin-ichiro Uchiumi, Kikuo Ataka, and Tokuo Matsuzaki).
• Palladium Catalyzed Enantioselective Rearrangements
of Allylic Imidates to Allylic Amides. (T.K. Hollis, L.E. Overman, and G.G. Zipp).
• Reactions of Si-Si bonds Catalyzed by Palladium(O)-Isonitrile
Complexes. (Yoshihiko Ito).
| Bibliographic details |
Hardbound, 0 pages, publication date: NOV-1999
ISBN-13: 978-0-444-50197-4
ISBN-10: 0-444-50197-5
Imprint: ELSEVIER
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| Price and Ordering |
Price:
GBP 144 USD 235 EUR 169.95
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Last update: 4 Sep 2009
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