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| CHEMISTRY OF TANTALUM AND NIOBIUM FLUORIDE COMPOUNDS
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By
Anatoly Agulyansky, Fluortech Ltd, Lehavim, Israel
Description
Electronic, optical, mechanical and medical appliances are just a few examples of modern applications that use tantalum and niobium. In Chemistry of Tantalum and Niobium Fluoride Compounds, the author draws on thirty years' experience to produce the first
ever monograph to systemize and summarize the data available on tantalum and niobium fluoride compounds. This comprehensive reference
source offers a rich variety of study methodology and is invaluable to researchers examining the chemistry of fluorides, as well as teachers
and students in chemistry and metallurgy.
Audience
Tantalum and niobium producers; researchers studying the chemistry of fluorides, teachers and students in chemistry and metallurgy
Contents
1. Introduction
1.1. General information on the application of tantalum and niobium
1.2. Tantalum and niobium
raw materials
1.3. Refining processes
1.4. Material science aspects
2. Synthesis of tantalum and niobium fluoride
compounds
2.1. Aqueous solutions
2.2. Non-aqueous solutions
2.3. Interactions with TaF5 and NbF5
2.4. Synthesis of fluoride compounds using NbO2F and TaO2F
2.5. Hydrofluoride synthesis of niobium and
tantalum compounds
3. Crystal chemistry of tantalum and niobium fluoride compounds
3.1. Island-type structure
compounds
3.2. Compounds with chain-type structure
3.3. Compounds with layered-type structure
3.4. Compounds with framework-type
3.5. Compounds with coordination-type structure
3.6. Crystal chemical classification
4. Tantalum and niobium complexes
in fluoride solutions
4.1. Niobium containing solutions
4.2. Tantalum containing solutions
5. Tantalum
and niobium complexes in fluoride melts
5.1. Preliminary notes
5.2. Melting diagrams
5.3. Physicochemical properties
5.4. Vibration spectroscopy of fluoride melts
5.5. Main conclusions
6. Thermal properties and decomposition of
tantalum-and niobium-containing fluoride compounds
6.1. Impact of temperature on solid fluoride complexes
6.2. Melting
processes
6.3. Thermal decomposition of oxyfluoroniobates
6.4. Gaseous components
6.5. Main conclusions
7.
Ferroelectric properties of niobium and tantalum fluoride compounds
7.1. General notes
7.2. Compounds derived from
lithium metatantalate
7.3. Spontaneous polarization and non-linear optic effect in niobium and tantalum fluoride compounds
7.4. Piezoelectric, pyroelectric and related properties in M5Nb3OF18 compounds
8. Fluorine
chemistry in the processing of tantalum and niobium
8.1. General notes
8.2. Raw material decomposition
8.3. Liquid-liquid
extraction
8.4. Preparation of tantalum and niobium oxides
8.5. K salt production
8.6 The production of tantalum and niobium
metals by reduction of fluoride melts
9. Main principals of the chemistry of tantalum and niobium fluoride compounds
Appendix
(X ray powder diffraction data of some important tantalum and niobium fluoride compounds)
Niobium-containing compounds
Tantalum-containing
compounds
| Bibliographic details |
Hardbound, 408 pages, publication date: OCT-2004
ISBN-13: 978-0-444-51604-6
ISBN-10: 0-444-51604-2
Imprint: ELSEVIER
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Last update: 10 Sep 2009
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