Nanoalloys

From Fundamentals to Emergent Applications

Edited by
  • Florent Calvo, LASIM, CNRS and University of Lyon, Villeurbanne, France

Hardbound, 400 Pages

Published: April 2013

Imprint: Elsevier

ISBN: 978-0-12-394401-6

Contents

  • Chapter I Chemical Syntheses

    Redox reactions; Polyol-based synthesis; radiolysis; electrochemical synthesis; thermal decomposition and sonochemical synthesis

    Chapter II Physical syntheses

    Molecular beam epitaxy; pulsed laser deposition; low-energy cluster beam deposition techniques

    Chapter III Modeling the Electronic and Geometric structure of nanoalloys

    Quantum chemical and condensed matter methods for electronic structure; Approximate descriptions and explicit models; global optimization; structural and segregation patterns

    Chapter IV Experimental techniques for structural characterization

    X-ray scattering and absorption; Electron microscopy; scanning probe microscopies: scanning tunneling and atomic force microscopies

    Chapter V Thermodynamical properties of nanoalloys

    Bulk vs nanoscale alloys; order/disorder transition; finite size effects; nanoscale phase diagrams; melting of nanoalloys

    Chapter VI Kinetic aspects: nucleation, mixing, coalescence

    Nucleation theories and models; Growth of nanoalloys; Mixing kinetics; coalescence

    Chapter VII Optical properties of nanoalloys / Nanoalloys as optical probes

    Linear optical spectroscopy; Mie theory and quantum confinement effects; Experimental techniques; Ultrafast pump-probe spectroscopy and electron-phonon couplings

    Chapter VIII Magnetic properties of nanoalloys / Nanoalloys for magnetic storage

    Magnetic moments and anisotropy; Experimental techniques; Magnetization configurations and role of chemical order; Kondo effect; Spin Dynamical effects

    Chapter IX Catalysis by Nanoalloys

    Preparation and characterization; Computational approaches; Various illustrations emphasizing the role of cluster size and composition

    Chapter X Nanoalloys in life sciences

    Biosynthesis of nanoalloys; Biofunctionalization; Applications as biosensors; imaging applications of nanoalloys; gene and vaccine delivery; Nanoalloys in pharmacology and toxicology

    Chapter XI Applications for energy production and storage

    Electrocatalysis; Nanoscale alloys for the reversible storage of hydrogen; Biofuel cells

    Chapter XII Nanoalloys as building blocks

    Assemblies of nanoalloys on substrates: preparation and characterization; Colloidal assemblies

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