Comprehensive Organometallic Chemistry III
Volume 10: Applications II - Transition metal organometallics in organic synthesis
Edited by- Iwao Ojima, State University of New York at Stony Brook, Stony Brook, NY, USA
Along with volume 11, this volume reviews how transition metal organometallic compounds are used in organic synthesis. Chapters cover one element and are sub-divided by type of reaction to be readily accessible by organic chemists. Classes of reactions reviewed include C-H, C-C, C-O, C-N and C-E bond formation (E= Si, Sn, B, Te, S, P)
Audience
Suitable for organic and inorganic chemists researchers and students in the fields of materials science and nanoscience. Practitioners working in industry who need to use or apply organometallic compounds.
Hardbound, 909 Pages
Published: November 2006
Imprint: Elsevier
ISBN: 978-0-08-044600-4
Contents
CH Bond Formation
10.01 CH Bond Formation by Asymmetric and Stereoselective Hydrogenation
10.02 CH Bond Formation: Through Isomerization
Synthetic Reactions via CH Bond Activation
10.03 Synthetic Reactions via CH Bond Activation: CC and CE Bond Formation
10.04 Synthetic Reactions via CH Bond Activation: Carbene and Nitrene CH Insertion
10.05 Synthetic Reactions via CH Bond Activation: Oxidation of CH Bonds
CC Bond Formation (Part 1) by Addition Reactions
10.06 CC Bond Formation (Part 1) by Addition Reactions: through Carbometallation Mediated by Group 47 Metals
10.07 CC Bond Formation (Part 1) by Addition Reactions: through Carbometallation Catalyzed by Group 811 Metals
10.08 CC Bond Formation through Conjugate Addition of CM to C=CC=O and C=CNO2
10.09 CC Bond Formation Through Addition of CM to C=O, C=N, and CN Bonds
10.10 Metal-catalyzed Reductive Carbocyclization (C=C, CC, C=O Bonds)
10.11 CC Bond Formation through Reaction of CO2 with CC and C=CC=C
10.12 CC Bond Formation (Part 1) by Addition Reactions: Alder-ene Reaction
10.13 CC Bond Formation (Part 1) by Addition Reactions: Higher-order Cycloadditions
CO and CN Bond Formation
10.14 CO Bond Formation through Transition Metal-mediated Etherification
10.15 CN Bond Formation through Amination
CE Bond Formation (E = Si, Sn, B, Te, S, P)
10.16 CE Bond Formation through ElementElement Addition to CarbonCarbon Multiple Bonds
10.17 CE Bond Formation through Hydrosilylation of Alkynes and Related Reactions
10.18 CE Bond Formation through Asymmetric Hydrosilylation of Alkenes
10.19 CE Bond Formation through Hydroboration and Hydroalumination
Index
