Comprehensive Organometallic Chemistry III

Volume 10: Applications II - Transition metal organometallics in organic synthesis

Edited by

  • Iwao Ojima, State University of New York at Stony Brook, Stony Brook, NY, USA

Along with volume 11, this volume reviews how transition metal organometallic compounds are used in organic synthesis. Chapters cover one element and are sub-divided by type of reaction to be readily accessible by organic chemists. Classes of reactions reviewed include C-H, C-C, C-O, C-N and C-E bond formation (E= Si, Sn, B, Te, S, P)
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Audience

Suitable for organic and inorganic chemists researchers and students in the fields of materials science and nanoscience. Practitioners working in industry who need to use or apply organometallic compounds.

 

Book information

  • Published: November 2006
  • Imprint: ELSEVIER
  • ISBN: 978-0-08-044600-4


Table of Contents

C–H Bond Formation
10.01 C–H Bond Formation by Asymmetric and Stereoselective Hydrogenation
10.02 C–H Bond Formation: Through Isomerization
Synthetic Reactions via C–H Bond Activation
10.03 Synthetic Reactions via C–H Bond Activation: C–C and C–E Bond Formation
10.04 Synthetic Reactions via C–H Bond Activation: Carbene and Nitrene C–H Insertion
10.05 Synthetic Reactions via C–H Bond Activation: Oxidation of C–H Bonds
C–C Bond Formation (Part 1) by Addition Reactions
10.06 C–C Bond Formation (Part 1) by Addition Reactions: through Carbometallation Mediated by Group 4–7 Metals
10.07 C–C Bond Formation (Part 1) by Addition Reactions: through Carbometallation Catalyzed by Group 8–11 Metals
10.08 C–C Bond Formation through Conjugate Addition of C–M to C=C–C=O and C=C–NO2
10.09 C–C Bond Formation Through Addition of C–M to C=O, C=N, and CN Bonds
10.10 Metal-catalyzed Reductive Carbocyclization (C=C, CC, C=O Bonds)
10.11 C–C Bond Formation through Reaction of CO2 with CC and C=C–C=C
10.12 C–C Bond Formation (Part 1) by Addition Reactions: Alder-ene Reaction
10.13 C–C Bond Formation (Part 1) by Addition Reactions: Higher-order Cycloadditions
C–O and C–N Bond Formation
10.14 C–O Bond Formation through Transition Metal-mediated Etherification
10.15 C–N Bond Formation through Amination
C–E Bond Formation (E = Si, Sn, B, Te, S, P)
10.16 C–E Bond Formation through Element–Element Addition to Carbon–Carbon Multiple Bonds
10.17 C–E Bond Formation through Hydrosilylation of Alkynes and Related Reactions
10.18 C–E Bond Formation through Asymmetric Hydrosilylation of Alkenes
10.19 C–E Bond Formation through Hydroboration and Hydroalumination
Index