Comprehensive Organometallic Chemistry III book cover

Comprehensive Organometallic Chemistry III

Volume 11: Applications III - Transition metal organometallics in organic synthesis 2

Along with volume 10, this volume reviews how transition metal organometallic compounds are used in organic synthesis. Chapters are organised by reaction type to be readily accessible by organic chemists. Classes of reactions reviewed include C-C bond formation, reaction of double bonds, metathesis reactions, carbonylation and polymer synthesis.

Audience

Suitable for organic and inorganic chemists researchers and students in the fields of materials science and nanoscience. Practitioners working in industry who need to use or apply organometallic compounds.

Hardbound, 766 Pages

Published: November 2006

Imprint: Elsevier

ISBN: 978-0-08-044601-1

Contents

  • C–C Bond Formation (Part 2) By Cross-Coupling
    11.01 C–C Bond Formation by Cross-coupling
    11.02 Reductive Coupling Reactions Promoted by Low-valent Early Transition Metals and Lanthanoids
    C–C Bond Formation (Part 2) By Substitution Reactions
    11.03 C–C Bond Formation (Part 2) by Substitution Reactions: Allylic Alkylation
    11.04 C–C Bond Formation (Part 2) by Substitution Reactions: Substitution at Propargylic and Benzylic Positions Synthetic Reactions of MTC and MTN Bonds
    11.05 Synthetic Reactions of MTC and MTN Bonds: Ylide Formation, Rearrangement, and 1,3-Dipolar Cycloaddition
    Metathesis Reactions
    11.06 Olefin Cross-Metathesis
    11.07 Ring-closing Olefin Metathesis for Organic Synthesis
    11.08 Ene–Yne and Alkyne Metathesis
    Simultaneous C–C and Other Bond Formation
    11.09 Sequential Formation of More than One C–C and Other Bonds by Multiple Heck-type Reactions
    11.10 Pauson–Khand Reaction
    11.11 Silane-initiated Carbocyclization Catalyzed by Transition Metal Complexes
    Carbonylation
    11.12 Carbonylative Cross-coupling and Carbocyclization
    11.13 Hydroformylation, Other Hydrocarbonylations, and Oxidative Alkoxycarbonylation
    11.14 Silylformylation
    11.15 Amidocarbonylation, Cyclohydrocarbonylation, and Related Reactions
    Transition Metal Catalysts in Polymer Synthesis
    11.16 Polymerization of Acetylenes
    11.17 Polymerization of Epoxides
    11.18 Ring-opening Metathesis Polymerization (ROMP)
    11.19 Cross-coupling Polymerization
    11.20 Polymerization of Alkenes
    Index

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